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Search "Organometallic compounds; infrared; raman; vibrational spectroscopy; vibrational spectra; organometallic; hydrocarbons; vibrational spectra of organometallic compounds; surface chemistry; spectroscopy; HREEL spectroscopy; matrix isolation spectroscopy; surface species; organic synthesis; industrial catalysis density; functional theory; spectroscopy; DFT; organometallic chemistry; direct metal‐carbon bonds; vibrational data applications; organometallic complexes; carbide"