Tautomerism: Methods and Theories

Covering the gap between basic textbooks and over-specialized scientific publications, this is the first reference available to describe this interdisciplinary topic for PhD students and scientists starting in the field.

The result is an introductory description providing suitable practical examples of the basic methods used to study tautomeric processes, as well as the theories describing the tautomerism and proton transfer phenomena. It also includes different spectroscopic methods for examining tautomerism, such as UV-VIs, time-resolved fluorescence spectroscopy, and NMR spectroscopy, plus the theoretical and practical background information.

With its excellent overview of the methods, theories and examples, this is the perfect guide for any scientist dealing with tautomeric compounds in a wider context.

Keywords: Tautomerism, Liudmil Antonov, Absorption UV-Vis spectroscopy and chemometrics, Application of NMR spectroscopy to tautomerism studies, isotope effects on chemical shifts as a tool in the study of tautomeric equilibria, the basicity method for the estimation of tautomer ratio, quantum chemical calculations of tautomeric equilibria force field treatment of proton and hydrogen transfer in molecular systems