Login

Maretina, Irina A.

Alkynes in Cycloadditions

Maretina, Irina A. - Alkynes in Cycloadditions, ebook

180,30€

Ebook, ePUB with Adobe DRM
ISBN: 9781118709290
DRM Restrictions

Printing94 pages with an additional page accrued every 8 hours, capped at 94 pages
Copy to clipboard5 excerpts

Acetylene systems present a new route to cyclic compounds as an alternative to more traditional methods employed in classical organic chemistry. The synthesis of cyclic structures based on acetylene systems has important applications in the formation of nanostructures, naturally occurring compounds and chemosensory materials for the design of nonlinear optics, electronic and photonic devices.

Alkynes in Cycloadditions presents a modern review of regioselective synthesis of aromatic and non-aromatic carbocyclic and heterocyclic ring systems based primarily on [2+2+2] and [4+2] cycloadditions, and other reactions of acetylenic units including enediynes and enyne-allenes.

Topics covered include:

  • New strategies for the formation of aromatic and polynuclear hydrocarbons based on (Z)-hex-3-en-1,5-diyne and (Z)-hepta-1,2,4-triene-6-yne blocks.
  • One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes by the cycloaromatization of enediynes and enyne-allenes by Bergman, Myers-Saito and Shmittel.
  • Mechanisms of cycloaromatization resulting in the formation of fulvene and indene systems.
  • Heterocyclization involving enyne-carbodiimides.
  • New achievements in classical cycloaddition reactions such as the Diels-Alder condensation with acetylenic dienophiles and [2+2] cycloadditions with acetylene components

Alkynes in Cycloadditions presents a comprehensive summary of the literature on methods for the synthesis of ring systems from acetylenes for academic researchers working in the fields of organic synthesis, physical organic chemistry, organometallic chemistry, catalysis, materials science, nanomaterials and biochemistry.

Keywords: Organic Chemistry

Author(s)
 
Translator
Publisher
John Wiley and Sons, Inc.
Publication year
2014
Language
en
Edition
1
Page amount
312 pages
Category
Natural Sciences
Format
Ebook
eISBN (ePUB)
9781118709290
Printed ISBN
9781118615324

Similar titles